C. Gasification

Date: 2015-10-07; view: 521.

B. Coking and use of coke

Coke is a solid carbonaceous residue derived from low-ash, low-sulfur bituminous coal from which the volatile constituents are driven off by baking in an oven without oxygen at temperatures as high as 1,000 °C (2,000 °F) so that the fixed carbon and residual ash are fused together. Coke is used as a fuel and as a reducing agent in smelting iron ore in a blast furnace. Coke from coal is grey, hard, and porous and has a heating value of 24.8 million Btu/ton (29.6 MJ/kg). Byproducts of this conversion of coal to coke include coal tar, ammonia, light oils, and "coal-gas".

Petroleum coke is the solid residue obtained in oil refining, which resembles coke but contains too many impurities to be useful in metallurgical applications.

High prices of oil and natural gas are leading to increased interest in "BTU Conversion" technologies such as coal gasification, methanation, liquification, and solidification.

Coal gasification breaks down the coal into its components, usually by subjecting it to high temperature and pressure, using steam and measured amounts of oxygen. This leads to the production of carbon dioxide and oxygen, as well as other gaseous compounds.

In the past, coal was converted to make coal gas, which was piped to customers to burn for illumination, heating, and cooking. At present, the safer natural gas is used instead. South Africa still uses gasification of coal for much of its petrochemical needs.

Gasification is also a possibility for future energy use, as it generally burns hotter and cleaner than conventional coal and can thus spin a more efficient gas turbine rather than a steam turbine. It also makes for the possibility of zero carbon dioxide emissions even though the energy comes from the conversion of carbon to carbon dioxide. This is because gasification produces a much higher concentration of carbon dioxide than direct combustion of coal in air (which is mostly nitrogen). The higher concentrations of carbon dioxide makes carbon capture and storage more economical than it otherwise would be.