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Active VocabularyDate: 2015-10-07; view: 478. Unit 4. Origin in Source Beds C. Discussion Topics: 1. Physical and chemical properties of petroleum. 2. Heavy and light oils and their qualities.
Oil is believed to have been generated in significant volumes only in fine-grained sedimentary rocks (usually clays, shales, or clastic carbonates) by geothermal action on kerogen, leaving an insoluble organic residue in the source rock. The release of oil from the solid particles of kerogen and its movement in the narrow pores and capillaries of the source rock is termed primary migration. Accumulating sediments can provide energy to the migration system. Primary migration may be initiated during compaction as a result of the pressure of overlying sediments. Continued burial causes clay to become dehydrated by the removal of water molecules that were loosely combined with the clay minerals. With increasing temperature, the newly generated hydrocarbons may become sufficiently mobile to leave the source beds in solution, suspension, or emulsion with the water being expelled from the compacting molecular lattices of the clay minerals. The hydrocarbon molecules would compose only a very small part of the migrating fluids, a few hundred parts per million. Migration through carrier beds The hydrocarbons expelled from a source bed next move through the wider pores of carrier beds (e.g., sandstones or carbonates) that are coarser-grained and more permeable. This movement is termed secondary migration. The distinction between primary and secondary migration is based on pore size and rock type. In some cases, oil may migrate through such permeable carrier beds until it is trapped by a permeability barrier and forms an oil accumulation (Figure 3). In others, the oil may continue its migration until it becomes a seep on the surface of the Earth, where it will be broken down chemically by oxidation and bacterial action. Since nearly all pores in subsurface sedimentary formations are water-saturated, the migration of oil takes place in an aqueous environment. Secondary migration may result from active water movement or can occur independently, either by displacement or by diffusion. Because the specific gravity of the water in the sedimentary formation is considerably higher than that of oil, the oil will float to the surface of the water in the course of geologic time and accumulate in the highest portion of a trap.
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